| 苄基芳基醚重排催化反应的研究进展 |
| 投稿时间：2014-05-15 修订日期：2014-11-12 点此下载全文 |
| 引用本文：王重庆,马宁宁,杨超,刘世豪,朱驹,郑灿辉.苄基芳基醚重排催化反应的研究进展[J].药学实践杂志,2015,33(6):486~489 |
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| 中文摘要:苄基芳基醚(BPE)的重排反应在有机化学和药物合成中具有重要作用。综述BPE在三氟乙酸、磷钨酸、环糊精、熔融锡和三溴化铝等不同催化体系中的重排反应,并探讨其可能的反应机制。 |
| 中文关键词:苄基芳基醚 重排 磷钨酸 环糊精 熔融锡 苄基碳正离子 |
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| Research progress in the catalytic rearrangement reaction of benzyl phenyl ethers |
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| Abstract:The rearrangement reaction of benzyl phenyl ethers(BPE) plays an important role in the organic chemistry and drug synthesis. This paper briefly reviewed the rearrangement reaction and its possible mechanism in various catalytic systems, such as trifluoroacetic acid, phosphotungstic acid, cyclodextrin, molten tin and aluminium bromide. |
| keywords:benzyl phenyl ethers rearrangement phosphotungstic acid cyclodextrin molten tin benzylic cation |
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